Introduction
The global grain farming market is expected to grow from $1128.97 billion in 2020 to $1150.56 billion in 2021 at a CAGR of 1.9%. The small growth is due to companies rearranging their structure and operations as well as recovery from the impact of COVID-19. Market growth is expected to increase in coming years with a projected size of $1463.22 billion in 2025 at a CAGR of 6.4%. Grain market crops include wheat, barley, oats, corn, rice, beans, soybeans, and oilseeds. Asia Pacific is the largest region in the global grain farming market, accounting for 69% of the market in 2020 while North America accounts for 9%. The global grain mill products market is separate and was valued at $655.0 billion in 2018. It is expected to grow to $830.8 billion by 2026 with a CAGR of 3.4%. Flour is mostly created by grinding wheat, maize, and rice, with wheat accounting for nearly 85% of total global flour products. A number of factors are expected to fuel the increased growth in the grain and grain mills product market in coming years. There has been a notable increase in seed replacement rates over the last decade in growing markets, especially for cereal crops. The rate increase is mostly a result of the increased use of hybrid seed. Hybrid grain seed produces a hybrid by fertilizing an inbred variety having sterile pollen with pollen from plants of a different inbred variety that has fertile pollen. Thus, hybrid grains have two genetically different parents and can produce up to 30% more plant yield than comparable inbred varieties grown under the same conditions. In India from 2017 to 2018, the seed replacement rates in maize was around 80%. In China, it is estimated that almost 60% of the total planted area for rice is hybrid rice. Maize and rice are the second and third most produced agricultural commodities in the world behind sugarcane. Rice is the most important food crop with regard to human nutrition and caloric intake and it provides over one-fifth of the calories consumed worldwide by humans. Approximately 95% of rice is consumed by people. While more maize than rice is produced, a good percentage of maize is used for animal feed, corn ethanol, corn starch, and corn syrup. There is a high demand for functional flours which are specialized products that are manufactured and treated to have enhanced nutrient qualities with increased health benefits. Flour with reduced gluten requires the use of genetically modified wheat, rice, or maize. Grain products are an essential food source for both animals and humans.
By definition, grain analysis is monitoring grain quality for mycotoxin contamination, pesticide residue, nutritional value and composition, and physical characteristics such as size and weight. While the exact process for producing grains varies, all of them include primary processing methods of planting, harvesting, cleaning, sorting, and final processing through a plant that is typically automated to obtain the desired final product. There is an increasing demand for new methods of grain analysis to address challenges as methods of minimizing resources, maximizing output, and creating new products are evolving. The grain analysis market was valued at $1.95 billion in 2019 and is projected to reach $2.92 billion by 2027 while growing at a CAGR of 5.6%. A number of factors are expected to fuel the growth of the grain analysis market. There is an increasing number of government regulations worldwide related to the safety and quality of food grains as well as an increasing outbreak of foodborne diseases. Both of these factors are expected to drive the growth of the grain analysis market. Transgenic and genetically modified grains are a growing percentage of the grain market and these crops create imminent challenges in both testing methods and regulatory approval. Minimizing pesticide residue is important for both health reasons and optimizing the amount of pesticide used to save costs.
Much attention has been paid to the detection of the quality and safety of grains. The worldwide market for these products creates a need for rapid and cost-effective methods to analyze and classify quality, especially when considering the large amount of variability of grain products in the market. Moreover, consumer awareness of quality assurance amongst brands is a major factor in consumers’ decisions to purchase grain products. The implications of poor product quality spreading in today’s social media environment as well as the financial consequences of product recall can be devastating to a company’s bottom line. Traditional methods for analyzing grain products include wet chemistry methods and sensory analysis. These methods are time-consuming and expensive, especially when applied in an on-line setting. Developing rapid, non-invasive, cost-effective, and environmentally sound methods for quality testing has become a priority for grain manufacturers. One such method with potential for both laboratory and industrial testing of grain products is NIR spectroscopy.
Grain Varieties
Rice
Rice is the most widely consumed food in the world by humans and it is estimated that one-fifth of all worldwide caloric intake comes from rice. It is the third most produced agricultural commodity after sugarcane and maize, but a good portion of sugarcane and maize is used for other purposes besides human food, while approximately 95% of all rice produced is eaten by humans. More than 90% of rice is grown in Asia, principally in China, India, Indonesia, and Bangladesh. It can be eaten alone or used in a great variety of side dishes, main dishes, or soup. Varieties are classified as long, medium, and short grained. Extensive research for methods to fortify the nutritional content of rice has been conducted and continues to evolve because it is such an essential food in many countries for human nutrition. One important and controversial research topic is genetically engineered rice. Research continues on transgenic rice with properties such as herbicide tolerance, insect, bacteria, fungus, and virus resistance, grain yield, and nutritional quality. Chemical and physical parameters of interest in rice include starch components, protein, moisture, viscosity, and antioxidant parameters. Other important quality control parameters include adulteration detection, brand authenticity, transgenic discrimination, and pest infestation. New methods will continue to emerge for quality control testing of rice and NIR spectroscopy has been extensively studied for rice analysis.
Wheat
Wheat is cultivated worldwide and is grown on more land area than any other food crop. The trade market for wheat is larger than that of all other crops combined and worldwide production is over seven hundred million tons annually. Wheat is the leading source of vegetable protein in food and is also an important source of carbohydrates. It contains a number of healthy nutritional components, such as vitamins, dietary fiber, and phytochemicals. Wheat can be consumed as a whole grain or milled into flour. There are approximately thirty thousand wheat varieties grown worldwide. Different varieties not only have different nutritional properties, but are also suited to growing in different areas of the world based on their suitability to specific climates, soil, and other environmental factors. Consumption of wheat continues to increase and one reason for this is the unique properties of gluten proteins, which help facilitate the production of processed foods. Processed foods are in high demand, especially in Western markets and this demand continues to rapidly increase. Extensive research is conducted on transgenic varieties but to date, no genetically modified wheat is grown commercially anywhere in the world. There have been a few incidents of cross-contamination with commercial wheat that have been controversial. Chemical and physical parameters of interest in wheat quality control include moisture, protein, starch, gluten content, fiber components, and sugars. Other important quality control parameters are origin authentication, adulteration detection, and wild vs. transgenic discriminant analysis. New methods will continue to emerge for quality control testing of wheat and NIR spectroscopy has been extensively studied for wheat analysis.
Flour
Flour is an important staple food and is used to make numerous products, such as bread, pasta, noodles, crackers, cakes, and pastries. Wheat is the most common grain used to make flour, accounting for about 85% of all flour produced and the term “flour” typically refers to wheat flour unless another type of flour is prevalent in that part of the world. Flour can also be made from rice, rye, barley, millet, quinoa, buckwheat, and oats. Some flours are made from non-grain products as well, such as roots, beans, nuts, and seeds. Flour consists of the endosperm, germ, and bran together (known as whole grain flour) or of the endosperm alone (refined flour). Many refined flours are bleached with a whitening agent to make white flour. This process significantly reduces nutritional content and nutrients are usually added after the bleaching process. The two main components of flour are starches and proteins. Higher protein flour is harder and stronger and is typically used to make crusty or chewy breads. Lower protein flour is softer and better suited for baked goods. Development of gluten-free flour has become a priority as a sizeable portion of people suffer from celiac disease, wheat allergies, and other ailments that do not allow them to consume gluten in appreciable quantities. Chemical and physical parameters of interest in flour include moisture, protein, starch components, fat, and ash. Other important quality control parameters include adulteration detection, blend content, and species discriminant analysis. New methods will continue to emerge for quality control testing of flour and NIR spectroscopy has been extensively studied for flour analysis.
Corn
Corn is also referred to as maize and in general, the two terms are synonymous. It is a domesticated grass that first emerged nearly seven thousand years ago in Mexico when humans first learned how to cross-pollinate plants. It is produced more than any other cereal grain crop worldwide and is used for human consumption, livestock feed, fuel, and processed into corn starch which has numerous food and non-food uses. It is estimated that 60% to 70% of corn produced worldwide is used for animal feed while the remainder is used for human food, fuel, and corn-based products. The evolution of different biotypes has created corn species that can grow from the tropics to the northern temperate zone, at sea level to twelve thousand feet above it, and with growing periods ranging from six weeks to thirteen months. Corn can be processed by dry milling or wet milling. Dry milling is typically used for ethanol production and focuses on physical separation of the endosperm from the germ and pericarp without the use of wet chemicals. Wet milling focuses on starch production and the product can later be processed into a variety of starch-based products or further refined into liquid or dry sweeteners. Research of genetically modified corn is extensive and while transgenic corn has great potential for development of drought, pest, and disease resistant varieties as well as helping to increase yield per acre, the practice is controversial. Chemical and physical parameters of interest in corn include carbohydrates, starch, protein, fiber parameters, lignin content and structure, and sugars. Other important quality control parameters include sweet and supersweet corn cultivar and seed sorting, silage nutritional value, transgenic vs. non-transgenic discriminant analysis, and nutrient content as a breeding selection tool. New methods will continue to emerge for quality control testing of corn and NIR spectroscopy has been extensively studied for corn analysis.
Oilseeds
Oilseeds are defined as the seed (endosperm) of any of several plants that are used commercially as a source of vegetable oil and can also refer to the plant that yields any such seed. Examples include groundnuts/peanuts, sunflower, sesame, safflower, linseed, soybean, rapeseed/canola, and palm kernel oil. They are crushed to obtain oil for human consumption and biodiesel production. The leftover material after crushing is processed into meal which is used for high protein livestock and poultry feed. Soybeans account for over half of all oilseeds produced worldwide and soybean oil has become so prevalent in the United States that the term “vegetable oil” is synonymous with soybean oil. Demand and trade are steadily increasing due to many factors, especially greater demand from China. There are regulations for the processing of soybeans into oil and meal related to specific processes and nutritional content. One of these is the inclusion of soybean hulls in the soybean meal, known as dehulled meal vs. non-dehulled meal. Yield per acre can vary greatly between different types of oilseeds. Soybeans typically produce about sixty gallons of oil per acre while rapeseed and canola can produce yields as high as two hundred and fifty gallons per acre. Soybean is commonly grown as a rotation crop with corn in the United States. The quality of oilseeds and oil is greatly dependent on the crop species and environmental conditions when growing, making quality control monitoring of utmost importance. Chemical and physical parameters of interest in oilseeds include oil content and yield, moisture, protein, fatty acids, lipids, carbohydrates, ash, and amino acids. Other quality control parameters include classification of viable and non-viable seeds, geographical origin, and variation based on species origin, country of origin, and light vs. dark seeds. New methods will continue to emerge for quality control testing of oilseeds and NIR spectroscopy has been extensively studied for oilseeds analysis.
Beans
Beans are a valuable food product for both humans and animals. They are the seeds of one of several genera of the flowering plant Fabaceae, which has nearly twenty thousand known species. Beans are valued for their health benefits, ease of transporting, long shelf-life, and high nutritional content. They can be cooked in numerous ways, such as boiling, frying, and baking. Popular bean varieties include green beans, lima beans, kidney beans, black beans, chickpeas, and soybeans. Beans are a major source of protein, dietary fiber, carbohydrates, minerals, and vitamins. Studies have shown numerous potential health benefits, such as reduction in blood sugar levels, lower blood pressure, and improved gut health. High fiber and healthy starches can help eaters feel full, helping to prevent overeating and facilitating weight loss. Demand for beans is surging due to numerous factors. The long-shelf life of beans makes it an ideal food for consumers to stock during the COVID-19 pandemic. Beans offer high protein and amino acid content while being much lower in calories and saturated fat than many high protein sources, such as meat and dairy products. Increased health awareness among consumers has increased demand for alternative health food sources that are high in protein and beans is an ideal such food. Other types of beans include coffee and cocoa beans and both coffee and chocolate are also seeing increased demand around the world. Chemical and physical parameters of interest include protein, moisture, starch, fat, oil, lipids, ash, carbohydrates, fiber, minerals, and seed germination time. Other quality parameters of interest in beans include macronutrient content based on contrasting tannins, species discrimination, and roasting level in coffee beans. New methods will continue to emerge for quality control testing of beans and NIR spectroscopy has been extensively studied for beans analysis.
Barley
Barley ranks fifth among all cereal crops in dry matter production in the world. It has a number of qualities that are favorable to growers, such as versatility, adaptability to unfavorable and changing climate and soil conditions, and superior properties for malting and brewing compared to other grains. It is also more tolerant to drought and saline soils than many other cereal grains. Nearly two-thirds of produced barley is used for animal feed. Approximately 30% is used for malting and brewing and the remainder is for human consumption. Energy content is slightly lower than most other grains because of higher fiber content, but the crude protein content is higher than that of corn and similar to wheat and oats. Malted barley is the preferred grain of brewers and is made by allowing the barley to germinate in water for a period of time, which prepares the starches for conversion into fermentable sugars. While barley is not a staple food in most countries, it is popular in Scandinavia and Eastern Europe. Interest in barley as a staple food is increasing as studies have shown it to be an excellent source of dietary fiber, complex carbohydrates as well as some minerals, vitamins, and antioxidant polyphenols. Barley has multiple classifications and the most important one is two-row barley vs. six-row barley, a distinction in the physical morphology of the plant. Both classifications have distinct advantages and disadvantages depending on both growing conditions and final use, especially for brewing. It can be processed into flour and milk as an alternative to traditional dairy products. Chemical and physical parameters of interest in barley include dry matter, nitrogen, starch, sugars, and viscosity. Other quality control parameters include mycotoxin detection, pest prevention, and the effect of herbicide on plant quality. New methods will continue to emerge for quality control testing of barley and NIR spectroscopy has been extensively studied for barley analysis.
Sorghum
Sorghum is the next most produced cereal grain after barley. It is a major food cereal in many Asian and African countries. Most varieties of sorghum are drought and heat tolerant as well as nitrogen efficient, making them an important grain in arid countries. It can be eaten whole or processed into multiple products. Sorghum flour is popular in China. Sorghum syrup or molasses is made in multiple countries and in India, popped sorghum is similar to popcorn with smaller puffs. As is the case with other grains, biochemical and physical properties like amylose, protein, and lipids can influence the rheological and sensory properties of the final processed product. For example, consistency of thick porridge is positively correlated with amylose but negatively with protein and lipids. Couscous and tortillas made from sorghum have similar correlations. Chemical and physical parameters of interest in sorghum include amylose, protein, lipids, moisture, endosperm texture, and hardness. Other quality control parameters include breeding analysis and pest, disease, and mycotoxin detections. New methods will continue to emerge for quality control testing of sorghum and NIR spectroscopy has been extensively studied for sorghum analysis.
Process Analytical Technology (PAT) & On-Line Measurements
Process Analytical Technology (PAT) is a framework for innovative process manufacturing and quality assurance. Critical points and parameters during manufacturing of a product are defined and the process is designed in a way that such points and parameters can be measured using analytical tools and instruments for real-time process feedback and control. Such instruments must be able to measure on-line and in a non-invasive manner. Many vendors have developed instruments that are able to measure multiple points in a process with a single instrument, usually using optical fibers and probes. PAT has become an important part of pharmaceutical as well as chemical manufacturing and is beginning to acquire a hold in the food & beverage industry. One such analytical tool with great potential for use in PAT is NIR spectroscopy.
There are significant challenges to implementing PAT in a grain manufacturing environment. NIR spectroscopy has been proven as a useful tool for measuring parameters of interest in the grain industry. Vendors are coming up with new and innovative ways to make on-line measurements a feasible solution for companies. Advances such as improved fiber-optics, in-situ sampling, a transition to integrated automation, improved data management systems, and communication systems in the Internet and Cloud age have all contributed to implementing PAT. The food and beverage industries also present particular challenges due to natural product variability. In the case of pharmaceuticals and chemicals, the manufacturing process is usually conducted in a controlled environment with constituents that rarely show variability in spectral data over time. For foods and particularly agricultural products, there can be marked differences in products due to many factors, such as temperature variability, seasonal variation, differences in soil and nutrients, and different breeds of the same product. Such variability is especially important to account for when performing grain analysis. Such differences can create variability in spectral data that must be incorporated into calibration models when calibrating NIR spectrometers and other analytical PAT tools. This is known as making models “robust” and often requires a larger and more incorporative sample set to achieve the desired results.
Calibration studies have been conducted for measuring parameters in the grain industry in-line as well as in the laboratory. Results have been good and show that in-line measurements are a feasible tool for grain analysis using PAT. Full adoption of PAT in the grain industry will require a collaborative effort from process engineers, food scientists, and other contributors to provide the industry with a manufacturing framework for the 21th century.
References
Grain Seed Market – Growth, Trends, COVID-19 Impact, and Forecasts (2021-2026)
https://www.mordorintelligence.com/industry-reports/cereals-and-grains-seed-market
Grain Farming Global Market Report 2021: COVID-19 Impact and Recovery to 2030
Grain Mill Products Market Size, Share & Trends Analysis Report By Product (Wheat, Rice), By Region And Segment Forecasts, 2019-2025
Functional Flours Market Size, Share, & Trends Analysis Report By Application, Regional Outlook, Competitive Strategies, And Segment Forecasts, 2019 To 2025
https://www.grandviewresearch.com/industry-analysis/functional-flours-market
Grain Analysis Market Size and Forecast
https://www.verifiedmarketresearch.com/product/grain-analysis-market/
Process Analytical Technology for the Food Industry -O’Donnell, Fagan, Cullen, et al., Springer, Food Engineering Series (2014)